Equations to know by heart

The MCAT doesn't give you a formula sheet. These 73 equations come up again and again. Each links to questions that make you apply it.

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Kinematics and forces

Velocity with constant acceleration

v = v0 + at

v final velocity, v0 initial velocity, a acceleration, t time

Use when time is given and distance isn't needed.

Practice 1 question →

Displacement with constant acceleration

Δx = v0t + ½at2

Δx displacement, v0 initial velocity, a acceleration, t time

From rest, this reduces to Δx = ½at². Free fall uses a = g.

Practice 3 questions →

Velocity–displacement relation

v2 = v02 + 2aΔx

v final velocity, v0 initial velocity, a acceleration, Δx displacement

The go-to equation when no time is given, such as stopping distances.

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Newton's second law

Fnet = ma

Fnet net force, m mass, a acceleration

Sum all forces first. On an incline, gravity's component along the ramp is mg sin θ.

Practice 3 questions →

Friction

f = μN

f friction force, μ coefficient of friction (static or kinetic), N normal force

On a flat surface with no vertical forces besides gravity, N = mg.

Practice 2 questions →

Centripetal acceleration and force

ac = v2/r  ·  Fc = mv2/r

v speed, r radius, m mass

Centripetal force isn't a new force; friction, tension, gravity, or a normal force supplies it.

Practice 4 questions →

Newton's law of gravitation

F = Gm1m2/r2

G gravitational constant, m1, m2 masses, r center-to-center distance

Inverse square: triple the distance, one-ninth the force. Measure r from the planet's center.

Practice 2 questions →

Torque

τ = rF sin θ

r lever arm, F force, θ angle between r and F

In rotational equilibrium, clockwise torques equal counterclockwise torques.

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Work, energy, momentum, and oscillation

Work

W = Fd cos θ

F force, d displacement, θ angle between them

Forces perpendicular to motion (normal force, magnetic force) do no work. Friction does negative work.

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Power

P = W/t = ΔE/t

W work, ΔE energy change, t time

Lifting at constant speed: P = mgh/t.

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Kinetic and gravitational potential energy

KE = ½mv2  ·  PE = mgh

m mass, v speed, g gravitational acceleration, h height

With no friction, mgh = ½mv², so v = √(2gh) regardless of mass. Doubling speed quadruples KE.

Practice 4 questions →

Springs (Hooke's law)

F = −kx  ·  U = ½kx2

k spring constant, x displacement from equilibrium

Force is linear in x; stored energy goes as x².

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Momentum and impulse

p = mv  ·  J = FΔt = Δp

p momentum, J impulse, F average force, Δt contact time

Momentum is conserved in every collision; kinetic energy only in elastic ones. Longer Δt means smaller force.

Practice 4 questions →

Pendulum period

T = 2π√(L/g)

T period, L length, g gravitational acceleration

Mass doesn't matter. Quadrupling the length doubles the period.

Practice 3 questions →

Fluids and gases

Density and specific gravity

ρ = m/V  ·  SG = ρ/ρwater

ρ density, m mass, V volume; ρwater = 1 g/cm³ = 1,000 kg/m³

SG above 1 sinks in water; for a floating object, SG = fraction submerged.

Practice 3 questions →

Pressure and Pascal's principle

P = F/A  ·  F1/A1 = F2/A2

P pressure, F force, A area

Convert area carefully: 1 cm² = 10⁻⁴ m².

Practice 2 questions →

Hydrostatic pressure

P = P0 + ρgh

P0 surface pressure, ρ fluid density, h depth

Gauge pressure is ρgh alone. About 10 m of water adds 1 atm.

Practice 2 questions →

Buoyant force (Archimedes)

Fb = ρfluidVsubg

ρfluid fluid density, Vsub submerged volume

Buoyant force = weight in air − apparent weight in fluid.

Practice 2 questions →

Continuity equation

A1v1 = A2v2

A cross-sectional area (πr²), v flow speed

Halving the radius cuts area to ¼, so speed rises 4×.

Practice 2 questions →

Bernoulli's equation

P + ½ρv2 + ρgh = constant

P pressure, ρ density, v speed, h height

Horizontal flow: faster means lower pressure. Use v₂² − v₁², not (v₂ − v₁)².

Practice 2 questions →

Poiseuille's law

Q = πr4ΔP/(8ηL)

Q flow rate, r radius, ΔP pressure difference, η viscosity, L length

Flow scales with r⁴: halving the radius cuts flow to 1/16.

Practice 2 questions →

Ideal gas law

PV = nRT  ·  P1V1/T1 = P2V2/T2

P pressure, V volume, n moles, R gas constant (0.0821 L·atm/mol·K), T temperature in kelvin

Always use kelvin. At STP, 1 mol occupies 22.4 L.

Practice 3 questions →

Dalton's law of partial pressures

PA = XAPtotal

PA partial pressure, XA mole fraction

Partial pressures add up to the total.

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Graham's law of effusion

r1/r2 = √(M2/M1)

r effusion rate, M molar mass

Lighter gases effuse faster, by the square root of the mass ratio.

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Electricity and magnetism

Coulomb's law and electric field

F = kq1q2/r2  ·  E = kq/r2

k = 9 × 10⁹ N·m²/C², q charge, r distance

Inverse square, like gravity. Fields from several charges add as vectors.

Practice 2 questions →

Electric potential and potential energy

V = kq/r  ·  W = qΔV

V potential, q charge, r distance, W work

Potential falls off as 1/r (not 1/r²) and is a scalar. 1 V = 1 J/C.

Practice 2 questions →

Uniform field between plates

E = V/d

E field strength, V potential difference, d plate separation

Convert d to meters.

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Ohm's law

V = IR

V voltage, I current, R resistance

Find total resistance first, then total current, then each branch.

Practice 2 questions →

Electrical power

P = IV = I2R = V2/R

P power, I current, V voltage, R resistance

In parallel (same V), the smaller resistor uses more power.

Practice 2 questions →

Resistors in series and parallel

Rs = R1 + R2  ·  1/Rp = 1/R1 + 1/R2

Rs series total, Rp parallel total

A parallel total is always smaller than the smallest branch.

Practice 3 questions →

Capacitance and stored energy

C = Q/V = κε0A/d  ·  U = ½CV2

C capacitance, Q charge, κ dielectric constant, A plate area, d separation

Capacitors combine opposite to resistors: add in parallel, reciprocals in series.

Practice 4 questions →

Magnetic force on a moving charge

F = qvB sin θ  ·  r = mv/(qB)

q charge, v speed, B field, θ angle between v and B, r radius of circular path

Zero force when moving parallel to the field. The force does no work.

Practice 3 questions →

Waves, sound, and light

Wave speed

v = fλ  ·  T = 1/f

v wave speed, f frequency, λ wavelength, T period

Frequency is set by the source; the medium sets speed, so λ changes between media.

Practice 1 question →

Sound level

β = 10 log(I/I0)

β sound level in dB, I intensity, I0 threshold intensity

Each 10× intensity adds 10 dB. Doubling distance from a point source quarters intensity (about −6 dB).

Practice 2 questions →

Doppler effect

f′ = f (v ± vo)/(v ∓ vs)

f′ observed frequency, v speed of sound, vo observer speed, vs source speed

Use the signs that raise f′ when source and observer approach.

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Standing waves

λ = 2L/n (both ends same)  ·  λ = 4L/n, n odd (one end closed)

λ wavelength, L length, n harmonic number

Strings and open pipes: all harmonics. Closed pipes: odd harmonics only.

Practice 2 questions →

Beat frequency

fbeat = |f1 − f2|

f1, f2 the two frequencies

The perceived pitch is the average; the beat rate is the difference.

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Photon energy

E = hf = hc/λ

h Planck's constant, f frequency, c speed of light, λ wavelength; hc ≈ 1,240 eV·nm

Shorter wavelength, more energy: violet beats red.

Practice 3 questions →

Index of refraction and Snell's law

n = c/v  ·  n1 sin θ1 = n2 sin θ2

n index of refraction, v speed in the medium, θ angle from the normal

Into higher n, light slows and bends toward the normal.

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Critical angle

sin θc = n2/n1

θc critical angle, n1 starting medium (higher n), n2 second medium

Total internal reflection only from higher to lower n.

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Thin lens and mirror equation

1/f = 1/o + 1/i  ·  m = −i/o  ·  f = R/2

f focal length, o object distance, i image distance, m magnification, R radius of curvature

Positive i: real and inverted. Negative i: virtual and upright.

Practice 4 questions →

Lens power

P = 1/f

P power in diopters, f focal length in meters

Converging lenses are positive, diverging negative. Lenses in contact add.

Practice 1 question →

Atoms and nuclei

Hydrogen energy levels

En = −13.6 eV/n2

En energy of level n

Photon energy = difference between two levels.

Practice 1 question →

Photoelectric effect

KEmax = hf − Φ

KEmax maximum electron energy, hf photon energy, Φ work function

Below threshold (hf less than Φ), no electrons at any intensity.

Practice 3 questions →

Radioactive decay

N = N0(½)t/t½

N amount remaining, N0 starting amount, t elapsed time, t½ half-life

Count halvings: 1/8 remaining means 3 half-lives.

Practice 2 questions →

Mass–energy equivalence

E = mc2

m mass in kg, c = 3 × 10⁸ m/s

Convert grams to kilograms before squaring c.

Practice 1 question →

Solutions, acids, and equilibrium

pH and pOH

pH = −log[H+]  ·  pH + pOH = 14

[H+] hydrogen ion concentration (M), at 25 °C

For a × 10⁻ⁿ, pH = n − log a. A larger coefficient lowers the pH a little.

Practice 3 questions →

Henderson–Hasselbalch

pH = pKa + log([A−]/[HA])

pKa of the acid, [A−] conjugate base, [HA] acid

Equal amounts: pH = pKa. Each 10× ratio shifts pH by 1.

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pH of a weak acid

[H+] ≈ √(KaC)

Ka acid dissociation constant, C initial concentration

Valid when the acid dissociates only slightly.

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Solubility product

Ksp = [Mn+]a[Xm−]b

ion concentrations at saturation, raised to their coefficients

MX: Ksp = s². MX₂: Ksp = 4s³. A common ion lowers solubility.

Practice 1 question →

Molarity and dilution

M = mol/L  ·  M1V1 = M2V2

M molarity, V volume

V₂ is the final volume, not the water added. Serial dilutions multiply.

Practice 2 questions →

Colligative properties

ΔT = iKm  ·  Π = iMRT

i van 't Hoff factor, K freezing or boiling constant, m molality, Π osmotic pressure, M molarity

NaCl gives i = 2, CaCl₂ gives i = 3, glucose gives i = 1.

Practice 3 questions →

Equilibrium constant and reaction quotient

K = [C]c[D]d/[A]a[B]b

concentrations at equilibrium (K) or at any moment (Q); leave out pure solids and liquids

Q less than K: forward. Q greater than K: reverse. Only temperature changes K.

Practice 2 questions →

Rate law

rate = k[A]m[B]n

k rate constant, m and n reaction orders (from experiments or the slow step)

Triple a second-order reactant: rate ×9. Halve a first-order one: rate ×½.

Practice 2 questions →

Thermodynamics and electrochemistry

Heat transfer

q = mcΔT  ·  q = mL

m mass, c specific heat, ΔT temperature change, L latent heat

During a phase change, temperature stays constant: use q = mL.

Practice 3 questions →

First law of thermodynamics

ΔU = Q − W

ΔU internal energy change, Q heat added, W work done by the system

Isothermal ideal gas: ΔU = 0, so Q = W.

Practice 2 questions →

Gibbs free energy

ΔG = ΔH − TΔS

ΔH enthalpy change, T temperature (K), ΔS entropy change

Match units: ΔS is usually in J/K, ΔH in kJ.

Practice 3 questions →

Free energy and the equilibrium constant

ΔG° = −RT ln K

R = 8.314 J/mol·K, T temperature (K), K equilibrium constant

K = 1 means ΔG° = 0. At 298 K, each 10× in K is about 5.7 kJ/mol.

Practice 2 questions →

Enthalpy from bond energies

ΔH = Σ bonds broken − Σ bonds formed

bond enthalpies in kJ/mol

Opposite of the products-minus-reactants rule used for heats of formation.

Practice 1 question →

Standard cell potential

E°cell = E°cathode − E°anode

standard reduction potentials of each half-cell

Don't multiply potentials by stoichiometric coefficients.

Practice 1 question →

Free energy and cell potential

ΔG° = −nFE°

n moles of electrons, F = 96,500 C/mol, E° cell potential

Positive E° means negative ΔG°: spontaneous (galvanic).

Practice 1 question →

Electrolysis (Faraday's law)

mol e− = It/F

I current (A), t time (s), F = 96,500 C/mol

Divide moles of electrons by the ion's charge to get moles of metal.

Practice 1 question →

Nernst equation

E = (61.5 mV/z) log([ion]out/[ion]in)

z ion charge, concentrations outside and inside the cell, at 37 °C

K⁺ is about −90 mV, Na⁺ about +60 mV. A divalent ion halves the factor.

Practice 2 questions →

Biochemistry and physiology

Michaelis–Menten

v = Vmax[S]/(Km + [S])

v reaction velocity, [S] substrate concentration, Km [S] at half Vmax

At [S] = Km, v = ½Vmax. Competitive inhibitors raise apparent Km.

Practice 3 questions →

Turnover number and catalytic efficiency

kcat = Vmax/[E]T  ·  efficiency = kcat/Km

[E]T total enzyme concentration

Watch time units when converting to s⁻¹.

Practice 2 questions →

Hardy–Weinberg

p + q = 1  ·  p2 + 2pq + q2 = 1

p, q allele frequencies; 2pq heterozygote frequency

Start from q² = the recessive phenotype frequency.

Practice 3 questions →

Isoelectric point

pI = (pKa1 + pKa2)/2

the two pKa values that bracket the neutral form

Acidic amino acids: average the two lowest. Basic: the two highest.

Practice 3 questions →

Cardiac output and blood pressure

CO = HR × SV  ·  MAP ≈ CO × TPR

HR heart rate, SV stroke volume, MAP mean arterial pressure, TPR total peripheral resistance

Changes multiply: double TPR and cut CO by 25%, MAP rises 1.5×.

Practice 2 questions →

Renal clearance

C = (U × V)/P

U urine concentration, V urine flow rate, P plasma concentration

Clearance above GFR means net secretion; below means net reabsorption.

Practice 2 questions →

Psych/Soc, statistics, and epidemiology

Weber's law

ΔI/I = k

ΔI just-noticeable difference, I starting intensity, k Weber fraction

The just-noticeable difference is a constant fraction, not a constant amount.

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z-score

z = (x − μ)/σ

x score, μ mean, σ standard deviation

In a normal distribution, z = 1 is about the 84th percentile; ±1 SD covers about 68%.

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Relative risk

RR = riskexposed / riskunexposed

risk = cases / people in the group

Risk difference (attributable risk) subtracts instead of divides.

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Sensitivity, specificity, and predictive values

Sens = TP/(TP + FN)  ·  Spec = TN/(TN + FP)  ·  PPV = TP/(TP + FP)

TP true positives, FN false negatives, TN true negatives, FP false positives

Sensitivity and specificity don't change with prevalence; PPV and NPV do.

Practice 3 questions →